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Chemistry MCQ Question - Electrochemistry
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1. In a galvanic cell
Chemical energy is converted into electricity
Chemical energy is converted into heat
Electrical energy is converted into chemical energy
Electrical energy is converted into heat
2. The degree of dissociation of week electrolyte increases as
Pressure increases
Dilution decreases
Dilution increases
None
3. Molten NaCl conducts electricity due to the presence of
Free electrons
Free molecules
Free ions
Atoms of Na and Cl
4. In which of the following reactions occur at cathode?
Cu2++2e-? Cu
Cu+2e-? Cu2+
Hg + O2 ? HgO
Mg + O2 ? MgO
5. Electricity in voltaic cell is produced due to
neutralization
oxidation
reduction
both b & c
6. In electrolytic solution conductance of electricity is due to
free electrons
ions
metals
electrodes
7. In electrolytic cell electricity carries
spontaneous reaction
non-wpontaneous reaction
neutralization
all of above
8. Reaction at anode is called
oxidation
reduction
redox
decomposition
9. In an electrolytic cell cathode provides electrons to
ve ion
?ve ion
neutral atom
does not provide any electron
10. In Galvanic cell electrons flow from anode to cathode through
external electric circuit
salt bridge
movement of ions
all of the above
11. Decrease in oxidation number is called
oxidation
reduction
oxidation-reduction
all of above represent same entity
12. For the measurement of standard electrode potential Zn is dipped in
1 M ZnO solution
1 M ZnSO4 solution
1.5 M ZnSO4 solution
0.1 M ZnSO4 solution
13. Right half cell contains __________ electrode
A1
Zn
Cu
Fe
14. Zn(s)/Zn+2(aq) 1M | | Cu+2(aq) 1M/Cu(s) is representation of reaction in
Daniel cell
Downs cell
Voltaic cell
Nelsons cell
15. Salt bridge transfers
electrons
anion
current
ions
16. Voltaic cell can be recharged by
by addition of fresh solution
by replacing external circuit with external source of electricity
by removal of solution
by heating it
17. E0red of an element cab be calculated by comparing it with
New electrode of same element
SHE
1M solution of ions of respective element
2M solution of HCI
18. Temperature for the measurement of standard electrode potential is
298K
300K
30?C
310K
19. H2 gas in SHE is filled at pressure of
760mm of Hg
750mm of Hg
780mm of Hg
800mm of Hg
20. Potential of SHE is considered as
zero
unity
constant
multiple of 1
21. Chemical used in salt bridge is
KOH
KCI
KNO3
KBr
22. Electrode potential of Zn is
oxidation
reduction
oxidation-reduction
depends on the nature of the coupled electrode
23. List of elements based on hydrogen scale is called
periodic table
groups
periods
electrochemical series
24. The element that act as anode always have _______ position in electrochemical cell
higher
lower
in middle
no effect of position
25. In galvanic cell Zn acts as an anode so its value of standard reduction potential in comparison to coupled electrode would be
greater
lesser
sum of reduction and oxidation potentials
none
26. Greater value of standard reduction potential greater will be tendency
to get oxidized
to get reduced
to accept electrons
both b and c
27. Greater value of standard reduction potential smaller will be tendency
to form positive ions
to form negative ions
gain electrons
all are possible
28. Secondary cell is
rechargeable
non rechargeable
electrolytic cell
Daniel cell
29. Lead accumulators are
secondary cell
primary cell
voltaic cell
both a & c
30. Density of H2SO4 in lead accumulator is
1.25g/cm3
1.3g/cm3
1.20g/cm3
1.15g/cm3
31. Capacity of one lead accumulator cell is
1.5 volts
2 volts
3 volts
1 volts
32. In alkaline battery the anode is made up of
MnO2
Zn
AgO2
cadmium
33. The strength of solution of an element whose electrode potential is to be measured is
2M
1N
1m
1M
34. Apparent charge on atom in molecule is
valency
coordination number
oxidation number
charge number
35. Voltaic cell is a
irreversible cell
reversible cell
alkaline cell
all of the above
36. In K2Cr2O7 the oxidation number of chromium is
7
6
-7
-6
37. Percentage of sulphuric acid in lead accumulator is
40%
25%
30%
50%
38. The reduction potential Zn is
0.76
-0.76
-0.55
0.55
39. The half cells are interconnected through
wire
salt bridge
electric circuit
no connection exists
40. I ? A elements are named as alkali metals because
Their oxides are basic
Their oxide and hydroxides are water soluble
Both a & b
They are found in earth
41. The word Alkali means
Base
Basic salt
Ashes
Spirit
42. Formula of Chile saltpetre is
NaNO3
CaCO3
Ba (NO3)2
NH4Cl
43. The elements which are very abundant in earth crust are
Si & A?
Ca & Mg
B & A?
All
44. The oxides of beryllium BeO is
Acidic
Basic
Amphoteric
Neutral
45. Which element is necessary for normal leaf development?
Si
Ba
Mg
Ca
46. Li is different from its family members due to
small size
high charge density
less electropositivity
all of the above
47. Carbonates of lithium are not stable like that of sodium due to
Low electronegativity
Low electropositivity
Low charge density
Not known yet
48. Nitrates of which pair of elements give different products on thermal decomposition?
Na K
Mg Ca
Li Na
Li Ca
49. Which one of the following is not an alkali metal?
Francium
Caesium
Rubidium
Radium
50. Which of the following sulphates is not soluble in water?
Sodium sulphate
Potassium sulphate
Zinc sulphate
Barium sulphate
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